Catalytic activity of a supported palladium-benzimidazole complex toward alkene hydrogenation

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Alexander, S. and Udayakumar, V. and Gayathri, V. (2012) Catalytic activity of a supported palladium-benzimidazole complex toward alkene hydrogenation. Transition Metal Chemistry, 37 (4). pp. 367-372. ISSN 1572-901X

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Official URL: https://doi.org/10.1007/s11243-012-9597-0

Abstract

A polymer anchored palladium complex was synthesized by sequential attachment of benzimidazole and palladium chloride to chloromethylated polystyrene divinyl benzene co-polymer with 6.5 cross-linking. The product was characterized by XPS, UV-vis. spectrophotometry, FTIR and TGA. Various physico-chemical properties such as bulk density, surface area and swelling behavior in different solvents were also measured. The polymer anchored complex was tested as a catalyst for reduction of olefins. The kinetics of hydrogenation of 1-hexene was studied by varying the temperature, catalyst concentration and substrate concentration. The energy and entropy of activation were evaluated from the kinetic data. The catalyst could be recycled a number of times and no leaching of metal from the catalyst surface was observed. © 2012 Springer Science+Business Media B.V.

Item Type: Article
Additional Information: cited By 2
Uncontrolled Keywords: 1-Hexene; Alkene hydrogenation; Benzimidazoles; Bulk density; Catalyst concentration; Catalyst surfaces; Chloromethylated polystyrene; Different solvents; Divinyl benzenes; Entropy of activation; FTIR; Kinetic data; Palladium chloride; Palladium complexes; Physicochemical property; Polymer anchored; Polymer anchored complexes; Polymer-supported; Rate equations; Substrate concentrations; Surface area; Swelling behavior, Benzene; Butadiene; Catalyst activity; Chemical properties; Chlorine compounds; Crosslinking; Hydrogenation; Kinetics; Leaching; Olefins; Palladium; Polymers; Polystyrenes, Palladium compounds
Subjects: Faculty of Science > Pure Sciences > Chemistry
Divisions: Jnana Bharathi / Central College Campus > Department of Chemistry
Depositing User: Mr. Kirana Kumar D
Date Deposited: 04 Apr 2016 06:21
Last Modified: 04 Apr 2016 06:21
URI: http://eprints-bangaloreuniversity.in/id/eprint/2728

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